Белоусов Юрий Александрович
Базовая кафедра неорганической химии и материаловедения Института общей и неорганической химии им. Н.С. Курнакова РАН
Профессиональные интересы
Должности
- Доцент — Базовая кафедра неорганической химии и материаловедения Института общей и неорганической химии им. Н.С. Курнакова РАН
Био
- · Начал работать в НИУ ВШЭ в 2020 году.
Образование
- 2013 · Кандидат наук
- 2008 · Специалитет: Московский государственный университет им. М.В. Ломоносова, специальность «Химия», квалификация «Химик»
Опыт работы
- · 2013 г: с Химический факультет МГУ им.Ломоносова, инженер (2013-2014), научный сотрудник (2014-2019), старший преподаватель( с
- · 2019г: )
- · 2014-2017: преподаватель химии школа №171 с углубленным изучением химии
- · 2017 г: с Физический институт им. П.Н.Лебедева РАН, научный сотрудник
Награды и поощрения
- · Надбавка за публикацию в журнале из Списка А (и приравненном к нему научном издании) (2025–2026, 2024–2025, 2023–2024)
- · Надбавка за публикацию в международном рецензируемом научном издании (2022–2023, 2021–2022)
- · Лучший преподаватель — 2023–2025
Гранты и проекты
- — · на соискание учёной степени кандидата наук
Идентификаторы исследователя
- ORCID:
0000-0002-4976-4437 - ResearcherID:
O-4904-2016 - Google Scholar: https://scholar.google.com/citations?hl=ru&user=BAWmkm0AAAAJ
Публикации (24)
New Heteroligand Europium and Gadolinium Formate Triazole Dicarboxylates: Synthesis, Structures, and Luminescence Properties
2020 · ARTICLE · en
Complexes {(NMe2H2)[Ln(TDA)(HCOO)] ∙ 0.5H2O)} are prepared by the solvothermal synthesis in a water–dimethylformamide (1 : 1) system from a mixture of 1,2,3-triazole-4,5-dicarboxylic acid (H3TDA), NaOH, and Ln(NO3)3 (Ln = Eu, Gd). The crystal structure of the europium complex is determined by X-ray structure analysis (CIF file CCDC no. 1939689). This compound is shown to be the ionic metal-organic framework, where the cavities in the anionic structure of [Eu(TDA)(HCOO)]– are partially occupied by the dimethylammonium cations and water molecules. The study of the luminescence spectra of the gadolinium derivative gives the energy of the triplet level of the H3TDA ligand (~25 300 cm–1), the value of which makes it possible to efficiently sensitize the luminescence of rare-earth metal ions, in particular, Eu3+. The decay kinetics and the emission and excitation spectra of the heterometallic derivatives {(NMe2H2)[Gd1 – xEux(TDA)(HCOO)] ∙ 0.5H2O)} are studied. The dilution of europium with gadolinium results in a substantial decrease in the concentration quenching of the europium luminescence and an increase in the observed lifetimes of the excited state of Eu3+.
Новые смешанолигандные формиаттриазолдикарбоксилаты европия и гадолиния: синтез, структура и люминесцентные свойства
2020 · ARTICLE · ru
Complexes {(NMe2H2)[Ln(TDA)(HCOO)] ∙ 0.5H2O)} are prepared by the solvothermal synthesis in a water–dimethylformamide (1 : 1) system from a mixture of 1,2,3-triazole-4,5-dicarboxylic acid (H3TDA), NaOH, and Ln(NO3)3 (Ln = Eu, Gd). The crystal structure of the europium complex is determined by X-ray structure analysis (CIF file CCDC no. 1939689). This compound is shown to be the ionic metal-organic framework, where the cavities in the anionic structure of [Eu(TDA)(HCOO)]– are partially occupied by the dimethylammonium cations and water molecules. The study of the luminescence spectra of the gadolinium derivative gives the energy of the triplet level of the H3TDA ligand (~25 300 cm–1), the value of which makes it possible to efficiently sensitize the luminescence of rare-earth metal ions, in particular, Eu3+. The decay kinetics and the emission and excitation spectra of the heterometallic derivatives {(NMe2H2)[Gd1 – xEux(TDA)(HCOO)] ∙ 0.5H2O)} are studied. The dilution of europium with gadolinium results in a substantial decrease in the concentration quenching of the europium luminescence and an increase in the observed lifetimes of the excited state of Eu3+.
Luminescent lanthanide-based sensor for H2O detection in aprotic solvents and D2O
2019 · ARTICLE · en
Applied methods for detecting water impurities in organic solvents, such as Fischer titration, include wayward equipment and toxic reagents. This method is inapplicable for detecting H2O in D2O, but suitable techniques like NMR-, IR-, and mass-spectrometry are costly. We report a low-cost, novel luminescent sensor material based on terbium-europium 3D MOF compound developed for facile, portable, and disposable monitoring of water quantities. Our sensor is able to determine water traces in D2O and aprotic organic solvents. Treating the material to solvent leads to the change in intensities ratio of terbium and europium bands in emission spectra depending of water content and nature of solvent. For D2O calibrating plot IEu/ITb – %H2O is linear whereas for dioxane and acetonitrile the dependence becomes linear in the coordinates IEu/ITb - ln(%H2O). The results reveal the potential application of developed sensor for ratiometric quantitation of H2O admixtures in D2O, organic solvents, transformer oil, etc.
Luminescent lanthanide-based sensor for H2O detection in aprotic solvents and D2O
2019 в печати · ARTICLE · en
Applied methods for detecting water impurities in organic solvents, such as Fischer titration, include wayward equipment and toxic reagents. This method is inapplicable for detecting H2O in D2O, but suitable techniques like NMR-, IR-, and mass-spectrometry are costly. We report a low-cost, novel luminescent sensor material based on terbium-europium 3D MOF compound developed for facile, portable, and disposable monitoring of water quantities. Our sensor is able to determine water traces in D2O and aprotic organic solvents. Treating the material to solvent leads to the change in intensities ratio of terbium and europium bands in emission spectra depending of water content and nature of solvent. For D2O calibrating plot IEu/ITb – %H2O is linear whereas for dioxane and acetonitrile the dependence becomes linear in the coordinates IEu/ITb - ln(%H2O). The results reveal the potential application of developed sensor for ratiometric quantitation of H2O admixtures in D2O, organic solvents, transformer oil, etc.
Курсы (2)
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Теоретическая неорганическая химия и химия элементов · 4 раза
2025/2026, 2024/2025, 2023/2024, 2022/2023 · Бакалавриат · рус
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Химия элементов
2021/2022 · Бакалавриат · рус